Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf
2 PublicationsMo K-edge EXAFS investigation of the [Mo7O24]6- promoted phosphate ester hydrolysis
van Deun, R.; Hennig, C.; Cartuyvels, E.; Nikitenko, S.; Parac-Vogt, T. N.
Abstract
The early transition metals (V, Nb, Ta, Mo, W) in their high oxidation states are able to form metal-oxygen clusters, commonly referred to as polyoxometallates (POMs). The diverse structures and compositions of polyoxometallates offer a wide versatility in terms of shape, polarity, redox potentials, surface charge distribution and acidity, and allow for numerous potential applications of POMs. The first reports describing the antitumoral activity of POMs appeared about ten years ago, and they have revealed that the antitumoral activity of [Mo7O24]6- is even better than that of commercial drugs. We have investigated the potential towards phosphate ester bond cleavage of the [Mo7O24]6- cluster.
Keywords: EXAFS; polyoxometallate; anti-tumor activity
-
Poster
23nd European Crystallographic Meeting, 06.-11.08.2006, Leuven, Belgium -
Abstract in refereed journal
Acta Crystallographica Section A 62(2006), s206
ISSN: 90-8649-040-9
Permalink: https://www.hzdr.de/publications/Publ-8748
Years: 2023 2022 2021 2020 2019 2018 2017 2016 2015