Publications Repository - Helmholtz-Zentrum Dresden-Rossendorf

The nanospace of the van der Waals (vdW) gap between structural units of two-dimensional (2D) materials serves as a platform for growing unusual 2D systems through
intercalation and studying their properties. Various kinds ofmetal chlorides have previously been intercalated for tuning the properties of host layered materials, but the atomic structure of
the intercalants remains still unidentified. In this study, we investigate the atomic structural transformation of molybdenum(V) chloride (MoCl 5 ) after intercalation into
bilayer graphene (BLG). Using scanning transmission electron microscopy, we found that the intercalated material represents MoCl 3 networks, MoCl 2 chains, and Mo 5 Cl 10 rings. Giant lattice distortions and frequent structural transitions occur in the 2D MoCl x that have never been observed in metal chloride systems. The trend of symmetric to nonsymmetric structural
transformations can cause additional charge transfer from BLG to the intercalated MoCl x , as suggested by our density functional theory calculations. Our study deepens the understanding of the behavior of matter in the confined space of the vdW gap in BLG and provides hints at a more efficient tuning of material properties by intercalation for potential applications,
including transparent conductive films, optoelectronics, and energy storage.