RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Complexation Query Results


Surface Complex Formation Data:

Mineral: Quartz
Reference: S05
SCM Type: TL - Triple Layer
Ligand: Na<1+> - sodium
Site Type: »Si-OH
Equation: »SiOH + Na<1+>  ⇔  »SiO-Na + H<1+>
LogK: -4.5
Experiment: Literature
Ionic Strength: 1.0 mol/L
Temperature: 298.15 K
Fit Method: Unknown
Comment: calculation from literature values with standard SSA and SSD at ionic strength of 1M »Si-O<1-> + Na<1+> = »Si-O-Na logK = 1.7 »Si-OH = »Si-O<1-> + H<1+> pK2 = -logK = 6.2 sum »Si-OH + Na<1+> = »Si-O-Na + H<1+> logK= 1.7 -6.2 = -4.5
 
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