RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Site Query Results


Binding Site Data:


Mineral: Goethite
Reference: ES18
SCM Type: CDM - (CD-)MUSIC   (C1: 1.3 F/m2,  C2: 5.0 F/m2)
Ionic Strength: KNO3
Site Type: »Fe-singly
PZC:
pK1: 8.5   pK12.31 nm−2 (normalized): 8.89
pK2:   
Site Density in nm-2: 5.6500
Original Site Density: 5.65 sites / nm² surface
Solid/Liquid Ratio in g/L: 0.15
pH Range: 3,5-11
Temperature in K: 294.0
Method for Site Density: Geometrical Calculation
Method for Protolysis:Electrophoretic Mobility
Fit Method:FITEQL
Comment: protonation of the singly and triply coordinated sites to form ≡FeOH2+0.5 and ≡Fe3OH+0.5 are described by a single pKa, which was set to the measured isoelectric point of the goethite; SSD (Fe-singly) was computed using ns = (STAN)/(1018aSA), where AN is the Avogadro constant; SSD (Fe-triply) taken from [TE02] and [AAFLA05], the inner-Helmholtz capacitance C1 was optimized in FITEQL using the Sb(V) adsorption envelop data; C2 = 5 F/m² [AAFLA05]
 
1 data sets were retrieved