Show Detailed Site Query Results
Binding Site Data:
Mineral: |
Goethite |
Reference: |
ES18 |
SCM Type: |
CDM - (CD-)MUSIC
(C1: 1.3 F/m2, C2: 5.0 F/m2) |
Ionic Strength: |
KNO3
|
Site Type: |
»Fe-triply |
PZC: |
|
pK1: |
8.5 |
|
pK12.31 nm−2 (normalized): |
8.57 |
pK2: |
|
| |
Site Density in nm-2: |
2.7000 |
Original Site Density: |
2.7 sites / nm² surface
|
Solid/Liquid Ratio in g/L: |
0.15 |
pH Range: |
3,5-11 |
Temperature in K: |
294.0 |
Method for Site Density: |
Geometrical Calculation |
Method for Protolysis: | Electrophoretic Mobility |
Fit Method: | FITEQL |
Comment: |
protonation of the singly and triply coordinated sites to form ≡FeOH2+0.5 and ≡Fe3OH+0.5 are described by a single pKa, which was set to the measured isoelectric point of the goethite; SSD (Fe-singly) was computed using ns = (STAN)/(1018aSA), where AN is the Avogadro constant; SSD (Fe-triply) taken from [TE02] and [AAFLA05], the inner-Helmholtz capacitance C1 was optimized in FITEQL using the Sb(V) adsorption envelop data; C2 = 5 F/m² [AAFLA05] |
|
1 data sets were retrieved
|