RES³T - Rossendorf Expert System for Surface and Sorption Thermodynamics

Show Detailed Site Query Results


Binding Site Data:


Mineral: Bentonite
Reference: HM10
SCM Type: DDL - Diffuse Double Layer
Ionic Strength: 0.053 mol/L of ground water
Site Type: »Si-OH
PZC:
pK1: pK1°I=0 (Conversion to I = 0):  
pK2: 7.62 pK2°I=0 (Conversion to I = 0): 7.53 pK22.31 nm−2 (normalized): 7.66
Site Density in nm-2: 2.1204
Original Site Density: 0.000125 mol / g solid
Solid/Liquid Ratio in g/L: 4.0
pH Range:
Temperature in K:
Method for Site Density: Potentiometric Titration
Method for Protolysis:Potentiometric Titration
Fit Method:PHREEQC
Comment: values from [HMSGB02] but there the constant capacitance model was used; 0.053m at pH=7.4 and 0.068m at pH=8.2; bentonite MX-80 with 80-84% montmorillonite, CEC = 76meq/100mg, The capacitance was introduced in the second paper [HMBF09]; also ion exchange reaction: »XNa + H<1+> = »XH + Na<1+> with logK = 1.0±0.05
 
1 data sets were retrieved