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2 PublicationsComplex Formation of Curium with Adenosine 5-Triphosphate (ATP) Studied by TRLFS
Moll, H.; Geipel, G.; Bernhard, G.
Abstract
We investigated for the first time the complex formation of curium(III) with adenosine 5-triphosphate (ATP) by time-resolved laser fluorescence spectroscopy (TRLFS). The interaction between soluble species of curium(III) with ATP was studied at trace Cm(III) concentrations (10-7 M), at different concentrations of ATP and at different pH using 0.154 M NaCl as background electrolyte. Predominant 1:1 complex formation reactions were observed. Taking the dissociation of H4ATP into consideration, we found evidence for the existence of three Cm ATP species: CmH2ATP+, CmHATP and CmATP-.
Keywords: Curium; TRLFS; Complexation; ATP
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Poster
Sixth International Conference on Nuclear and Radiochemistry (NRC 6), 29 August to 3 September 2004, Aachen, Germany -
Contribution to proceedings
Sixth International Conference on Nuclear and Radiochemistry (NRC 6), 19.08.-03.09.2004, Aachen, Germany
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