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Measurement of Diamond Nucleation Rates from Hydrocarbons at Conditions Comparable to the Interiors of Icy Giant Planets

Schuster, A. K.; Hartley, N. J.; Vorberger, J.; Döppner, T.; van Driel, T.; Falcone, R. W.; Fletcher, L. B.; Frydrych, S.; Galtier, E.; Gamboa, E. J.; Gericke, D. O.; Glenzer, S. H.; Granados, E.; Macdonald, M. J.; Mackinnon, A. J.; Mcbride, E. E.; Nam, I.; Neumayer, P.; Pak, A.; Prencipe, I.; Rohatsch, K.; Saunders, A. M.; Sun, P.; Kraus, D.

Abstract

We present measurements of the nucleation rate into a diamond lattice in dynamically compressed polystyrene obtained in a pump-probe experiment using a high energy laser system and in situ femtosecond X-ray diffraction. Different temperature-pressure conditions that occur in planetary interiors were probed. For a single shock reaching 70GPa and 3000K no diamond formation was observed while with a double shock driving polystyrene to pressures around 150GPa and temperatures around 5000K nucleation rates between 1029 m-3s-1 and 1034 m-3s-1 were recorded. These nucleation rates do not a agree with predictions of recent theoretical models for carbon-hydrogen mixtures by many orders of magnitude. Our data suggests that there is indeed significant diamond formation to be expected inside icy giant planets like Neptune and Uranus.

Permalink: https://www.hzdr.de/publications/Publ-28205


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