Mineral: |
Alumina |
Reference: |
S06c |
SCM Type: |
TL - Triple Layer
(C1: 0.9 F/m2) |
Ionic Strength: |
NaCl
|
Site Type: |
»Al-OH |
PZC: |
8.65 |
pK1: |
5.8 |
|
pK12.31 nm−2 (normalized): |
6.44 |
pK2: |
11.7 |
|
pK22.31 nm−2 (normalized): |
11.06 |
Site Density in nm-2: |
10.0000 |
Original Site Density: |
10.0 sites / nm² surface
|
Solid/Liquid Ratio in g/L: |
|
pH Range: |
|
Temperature in K: |
298.15 |
Method for Site Density: |
Method for Protolysis: | Literature |
Fit Method: | graphic extrapolation |
Comment: |
pK1 and pK2 were calculated from the values pH(ZPC) and deltapKn(0); equilibrium constants in this study refer to site-occupancy standard state with hypothtical 1.0 M ionic strength (K°) and values for N' = 10 * 10^18 m^-2 and A' = 10 m²/g using the equation: K = K°(Ns * As/N' * A'), where Ns represents the SSD = 8.0 sites/nm² from [HS73] and As the SSA = 100.0 m²/g from [HS73]; regression of proton surface charge data reported in [S05]; pH(ZPC): low ionic strength isoelectric point from [HS73] |
|