Helmholtz-Zentrum Dresden-Rossendorf
Chemie der f-Elemente
Herr Dr. Robert Gericke
SC-XRD & SQUID
Telefon
+49 351 260 2011
r.gerickehzdr.de
Link
ORCID: 0000-0003-4669-0206
Adresse
Gebäude/Raum
Bautzner Landstraße 400 - 01328 Dresden
801/P205
Scientific Career
- since 2023-05:Project leader (Am-BALL)
- 2021-02 to 2023-04:High Potential Program (HZDR)
- 2018-09 to 2020-12:Postdoctoral Research Fellow (CRANN / School of Chemistry / Trinity College Dublin, the University of Dublin: Dublin, IE)
- 2013-12 to 2018-01:PhD Student (Institut für Anorganische Chemie / Technische Universität Bergakademie Freiberg, Sachsen, DE)
- 2013-04 to 2013-09 :Research fellow (Centre for Advanced Materials and Industrial Chemistry (CAMIC) / School of Applied Sciences / RMIT University: Melbourne, Victoria, AU)
- 2012:Master of Science (Chemistry / Institut für Anorganische Chemie / Technische Universität Bergakademie Freiberg, Sachsen, DE)
Research Fields
- Metalorganic and coordination chemistry of the f-elements
- Single-crystal X-ray diffraction analysis
- SQUID magnetometry
- EPR spectroscopy
- Quantum chemical calculations
Projects
- ActiDecorp (DFG, 530101100)
- Am-BALL (BMUV, 1501667)
- FENABIUM II (BMBF, 02NUK077)
- f-Char (BMBF, 02NUK059)
Teaching
- Supervision of research internships, Master and PhD theses
Publications
2024
Preparation and characterization of Mn(II)Mn(III) complexes with relevance to class Ib ribonucleotide reductases
Doyle, L. M.; Bienenmann, R. L. M.; Gericke, R.; Xu, S.; Farquhar, E. R.; Que Jr, L.; McDonald, A. R.
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Journal of Inorganic Biochemistry 257(2024), 112583
DOI: 10.1016/j.jinorgbio.2024.112583
A Co(II)-Hydroxide Complex That Converts Directly to a Co(II)-Acetamide during Catalytic Nitrile Hydration
Heim, P.; Biswas, S.; Lopez, H.; Gericke, R.; Twamley, B.; McDonald, A. R.
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Inorganic Chemistry 63(2024), 7896-7902
DOI: 10.1021/acs.inorgchem.4c00754
Triply Bonded Pancake π-Dimers Stabilized by Tetravalent Actinides
Barluzzi, L.; Ogilvie, S. P.; Dalton, A. B.; Kaden, P.; Gericke, R.; Mansikkamäki, A.; Giblin, S. R.; Layfield, R. A.
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Journal of the American Chemical Society 146(2024)6, 4234-4241
DOI: 10.1021/jacs.3c13914
Optimisation of synthesis procedures and structural investigation of monazite-cheralite solid solutions
Lender, T.; Braga Ferreira Dos Santos, L.; Gericke, R.; Huittinen, N. M.; Peters, L.
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MRS Advances (2024)
DOI: 10.1557/s43580-024-00792-6
Cited 1 times in Scopus
2023
The Hexacoordinate Si Complex SiCl₄(4-Azidopyridine)₂—Crystallographic Characterization of Two Conformers and Probing the Influence of SiCl₄-Complexation on a Click Reaction with Phenylacetylen
Riedel, S.; Gerwig, M.; Gerlach, D.; Brendler, E.; Gericke, R.; Kroke, E.; Wagler, J.
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Inorganics 11(2023)12, 473
DOI: 10.3390/inorganics11120473
Lewis Acid-Base Adducts of α-Amino Acid-Derived Silaheterocycles and N-Methylimidazole
Seidel, A.; Gericke, R.; Kutzner, B.; Wagler, J.
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Molecules 28(2023)23, 7816
DOI: 10.3390/molecules28237816
Fate of Oxidation States at Actinide Centers in Redox-Active Ligand Systems Governed by Energy Levels of 5f Orbitals
Takeyama, T.; Tsushima, S.; Gericke, R.; Kaden, P.; März, J.; Takao, K.
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Chemistry - A European Journal 29(2023)69, e202302702
DOI: 10.1002/chem.202302702
Pd–Si complexes of the type ClPd(μ²-pyO)₄SiR (R = Me, Ph, Bn, Allyl, κO-(pyO)PdCl(η³-allyl); pyO = pyridine-2-olate): The influence of substituent R on the Pd–Si bond
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Polyhedron 245(2023), 116663
DOI: 10.1016/j.poly.2023.116663
Cited 2 times in Scopus
Ge–Cu-Complexes Ph(pyO)Ge(μ²-pyO)₂CuCl and PhGe(μ²-pyO)₄CuCl - Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems
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Molecules 28(2023)14, 5442
DOI: 10.3390/molecules28145442
Cited 1 times in Scopus
Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to [(Me3P)xM(2-C6F4PPh2)2] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions
Gericke, R.; Bennett, M. A.; Privér, S.; Bhargava, S.
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Inorganic Chemistry 62(2023)23, 8846-8862
DOI: 10.1021/acs.inorgchem.3c00311
Cited 1 times in Scopus
Evidence for a High-Valent Iron-Fluoride That Mediates Oxidative C(sp3)‐H Fluorination
Panda, C.; Anny-Nzekwue, O.; Doyle, L. M.; Gericke, R.; McDonald, A. R.
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JACS Au 3(2023), 919
DOI: 10.1021/jacsau.3c00021
Cited 7 times in Scopus
Synthesis and Characterization of a Masked Terminal Nickel-Oxide Complex
Heim, P.; Spedalotto, G.; Lovisari, M.; Gericke, R.; O’Brien, J.; Farquhar, E. R.; McDonald, A. R.
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Chemistry - A European Journal 29(2023)21, e202203840
DOI: 10.1002/chem.202203840
Cited 3 times in Scopus
Aromatic and aliphatic hydrocarbon hydroxylation via a formally Ni(IV)=O oxidant
Heim, P.; Gericke, R.; Spedalotto, G.; Lovisari, M.; Farquhar, E. R.; McDonald, A. R.
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Dalton Transactions 52(2023), 2663-2671
DOI: 10.1039/D2DT03949D
Cited 1 times in Scopus
Copper Complexes of Silicon Pyridine-2-olates RSi(pyO)₃ (R = Me, Ph, Bn, Allyl) and Ph₂Si(pyO)₂
Seidel, A.; Gericke, R.; Brendler, E.; Wagler, J.
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Inorganics 11(2023)1, 2
Online First (2022) DOI: 10.3390/inorganics11010002
Cited 4 times in Scopus
Deconvoluting Cr States in Cr-Doped UO2 Nuclear Fuels via Bulk and Single Crystal Spectroscopic Studies
Murphy, G. L.; Gericke, R.; Gilson, S.; Bazarkina, E.; Roßberg, A.; Kaden, P.; Thümmler, R.; Klinkenberg, M.; Henkes, M.; Kegler, P.; Svitlyk, V.; Marquardt, J.; Lender, T.; Hennig, C.; Kvashnina, K.; Huittinen, N. M.
Beteiligte Forschungsanlagen
- Rossendorf Beamline an der ESRF DOI: 10.1107/S1600577520014265
Verknüpfte Publikationen
- DOI: 10.1107/S1600577520014265 is cited by this (Id 35473) publication
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Data publication: Deconvoluting Cr States in Cr-Doped UO2 Nuclear Fuels via …
ROBIS: 36731 HZDR-primary research data are used by this (Id 35473) publication
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Nature Communications 14(2023), 2455
DOI: 10.1038/s41467-023-38109-0
Cited 3 times in Scopus
2022
Molecular Structures of the Silicon Pyridine-2-(thi)olates Me3Si(pyX), Me2Si(pyX)2 and Ph2Si(pyX)2 (py = 2-Pyridyl, X = O, S), and Their Intra- and Intermolecular Ligand Exchange in Solution
Seidel, A.; Weigel, M.; Ehrlich, L.; Gericke, R.; Brendler, E.; Wagler, J.
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Crystals 12(2022)8, 1054-1054
DOI: 10.3390/cryst12081054
Cited 4 times in Scopus
P–Ru-Complexes with a Chelate-Bridge-Switch: A Comparison of 2-Picolyl and 2-Pyridyloxy Moieties as Bridging Ligands
Ehrlich, L.; Gericke, R.; Brendler, E.; Wagler, J.
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Molecules 27(2022)9, 2778
DOI: 10.3390/molecules27092778
2021
Coordination and Electrochemical Switching on Paddle-Wheel Complexes Containing an As−Ru or a Sb−Ru Axis
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Inorganic Chemistry 60(2021)23, 18122-18132
DOI: 10.1021/acs.inorgchem.1c02735
Cited 4 times in Scopus
Rapid Iron(III)-Fluoride Mediated Hydrogen Atom Transfer
Panda, C.; Doyle, L. M.; Gericke, R.; McDonald, A. R.
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Angewandte Chemie - International Edition 60(2021)50, 26281-26286
DOI: 10.1002/anie.202112683
Cited 15 times in Scopus
Comparing Metal–Halide and −Oxygen Adducts in Oxidative C/O–H Activation: Au(III)–Cl versus Au(III)–OH
Lovisari, M.; Gericke, R.; Twamley, B.; McDonald, A. R.
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Inorganic Chemistry 60(2021), 15610-15616
DOI: 10.1021/acs.inorgchem.1c02222
Cited 10 times in Scopus